Analyzing Different Waste-to-Energy Technologies

Major components of Waste-to-Energy Processes

1. Front end MSW pre-processing is used to prepare MSW for treatment and separate any recyclables
2. Conversion unit (reactor)
3. Gas and residue treatment plant (optional)
4. Energy recovery plant (optional): Energy / chemicals production system includes gas turbine, boiler, internal combustion engines for power production. Alternatively, ethanol or other organic chemicals can be produced
5. Emissions clean up

Incineration

• Combustion of raw MSW, moisture less than 50%
• Sufficient amount of oxygen is required to fully oxidize the fuel
• Combustion temperatures are in excess of 850^oC
• Waste is converted into CO2 and water concern about toxics (dioxin, furans)
• Any non-combustible materials (inorganic such as metals, glass) remain as a solid, known as bottom ash (used as feedstock in cement and brick manufacturing)
• Fly ash APC (air pollution control residue) particulates, etc
• Needs high calorific value waste to keep combustion process going, otherwise requires high energy for maintaining high temperatures

Anaerobic Digestion

•  Well-known technology for domestic sewage and organic wastes treatment, but not for unsorted MSW
• Biological conversion of biodegradable organic materials in the absence of oxygen at temperatures 55 to 75^oC (thermophilic digestion – most effective temperature range)
• Residue is stabilized organic matter that can be used as soil amendment after proper dewatering
• Digestion is used primarily to reduce quantity of sludge for disposal / reuse
• Methane gas generated used for electricity / energy generation or flared

Gasification

• Can be seen as between pyrolysis and combustion (incineration) as it involves partial oxidation.
• Exothermic process (some heat is required to initialize and sustain the gasification process).
• Oxygen is added but at low amounts not sufficient for full oxidation and full combustion.
• Temperatures are above 650^oC
• Main product is syngas, typically has net calorific value of 4 to 10 MJ/Nm³
• Other product is solid residue of non-combustible materials (ash) which contains low level of carbon

Pyrolysis

• Thermal degradation of organic materials through use of indirect, external source of heat
• Temperatures between 300 to 850^oC are maintained for several seconds in the absence of oxygen.
• Product is char, oil and syngas composed primarily of O₂, CO, CO₂, CH₄ and complex hydrocarbons.
• Syngas can be utilized for energy production or proportions can be condensed to produce oils and waxes
• Syngas typically has net calorific value (NCV) of 10 to 20 MJ/Nm

Plasma Gasification

• Use of electricity passed through graphite or carbon electrodes, with steam and/or oxygen / air injection to produce electrically conducting gas (plasma)
• Temperatures are above 3000^oC
• Organic materials are converted to syngas composed of H2, CO
• Inorganic materials are converted to solid slag
• Syngas can be utilized for energy production or proportions can be condensed to produce oils and waxes

 

        Net Energy Generation Potential Per Ton MSW

Waste Management Method	Energy Potential* (kWh per ton MSW)
Recycling	2,250
Landfilling	105
WTE Incineration	585
Gasification	660
Pyrolysis	660
Anaerobic Digestion	250

Cost Economics of WTE Processes

Technology	Plant capacity (tons/day)	Capital cost (M US$)	O&M cost (US$/ton)	Planning to commissioning (months)
Pyrolysis	70-270	16 – 90	80 – 150	12 – 30
Gasification	900	15 – 170	80 – 150	12 – 30
Incineration	1300	30 – 180	80 – 120	54 – 96
Plasma gasification	900	50 – 80	80 – 150	12 – 30
Anaerobic digestion	300	20 – 80	60 – 100	12 – 24
In vessel composting	500	50 – 80	30 – 60	9 – 15
Sanitary landfill	500	5 – 10	10 – 20	9 – 15
Bioreactor landfill	500	10 – 15	15 – 30	12 – 18

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Composting

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The composting process is a complex interaction between the waste and the microorganisms within the waste. The microorganisms that carry out this process fall into three groups: bacteria, fungi, and actinomycetes.Actinomycetes are a form of fungi-like bacteria that break down organic matter. The first stage of the biological activity is the consumption of easily available sugars by bacteria, which causes a fast rise in temperature. The second stage involves bacteria and actinomycetes that cause cellulose breakdown. The last stage is concerned with the breakdown of the tougher lignins by fungi.

Central solutions are exemplified by low-cost composting without forced aeration, and technologically more advanced systems with forced aeration and temperature feedback. Central composting plants are capable of handling more than 100,000 tons of biodegradable waste per year, but typically the plant size is about 10,000 to 30,000 tons per year. Biodegradable wastes must be separated prior to composting: Only pure foodwaste, garden waste, wood chips, and to some extent paper are suitable for producing good-quality compost.

 The composting plants consist of some or all of the following technical units: bag openers, magnetic and/or ballistic separators, screeners (sieves), shredders, mixing and homogenization equipment, turning equipment, irrigation systems, aeration systems, draining systems, bio-filters, scrubbers, control systems, and steering systems. The composting process occurs when biodegradable waste is piled together with a structure allowing for oxygen diffusion and with a dry matter content suiting microbial growth. The temperature of the biomass increases due to the microbial activity and the insulation properties of the piled material. The temperature often reaches 65 degrees C to 75 degrees C within a few days and then declines slowly. This high temperature hastens the elimination of pathogens and weed seeds.

Biomass Energy Resources in Philippines

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Like any developing country, the Philippines is facing a formidable challenge of fostering sustainable energy options to support the energy requirements of its economic and social development goals with minimal adverse effects on the environment. In the Philippines, renewable energy sources contribute 43 percent to the country’s primary energy mix, one of the highest in Southeast Asia. The Philippines has an existing capacity of 5,500 MW of renewable energy power. Out of which, 61 percent is hydropower while 37 percent is geothermal power. Biomass energy application accounts for around 15 percent of the primary energy use in the country. The resources available in the Philippines can generate biomass projects with a potential capacity of around 200 MW.

The country has abundant supplies of biomass resources, offering much potential for clean energy generation.  These include agricultural crop residues, forest residues, animal wastes, agro-industrial wastes, municipal solid wastes and aquatic biomass. The most common agricultural wastes are rice hull, bagasse, coconut shell/husk and coconut coir. The use of crop residues as biofuels is increasing in the Philippines as fossil fuel prices continue to rise. Rice hull is perhaps the most important, underdeveloped biomass resource that could be fully utilized in a sustainable manner.

The Philippines is mainly an agricultural country with a land area of 30 million hectares, 47 percent of which is agricultural. The total area devoted to agricultural crops is 13 million hectares distributed among food grains, food crops and non-food crops. Among the crops grown, rice, coconut and sugarcane are major contributors to biomass energy resources. The most common agricultural residues are rice husk, rice straw, coconut husk, coconut shell and bagasse. The country has good potential for biomass power plants as one-third of the country’s agricultural land produces rice, and consequently large volumes of rice straw and hulls are generated.

A Glance at Biomass Resources

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Biomass energy projects provide major business opportunities, environmental benefits, and rural development.  Feedstocks can be obtained from a wide array of sources without jeopardizing the food and feed supply, forests, and biodiversity in the world.

Agricultural Residues

Crop residues encompasses all agricultural wastes such as bagasse, straw, stem, stalk, leaves, husk, shell, peel, pulp, stubble, etc. Large quantities of crop residues are produced annually worldwide, and are vastly underutilised. Rice produces both straw and rice husks at the processing plant which can be conveniently and easily converted into energy. Significant quantities of biomass remain in the fields in the form of cob when maize is harvested which can be converted into energy. Sugar cane harvesting leads to harvest residues in the fields while processing produces fibrous bagasse, both of which are good sources of energy. Harvesting and processing of coconuts produces quantities of shell and fibre that can be utilized.

Current farming practice is usually to plough these residues back into the soil, or they are burnt, left to decompose, or grazed by cattle. These residues could be processed into liquid fuels or thermochemical processed to produce electricity and heat. Agricultural residues are characterized by seasonal availability and have characteristics that differ from other solid fuels such as wood, charcoal, char briquette. The main differences are the high content of volatile matter and lower density and burning time.

Animal Waste

There are a wide range of animal wastes that can be used as sources of biomass energy. The most common sources are animal and poultry manures. In the past this waste was recovered and sold as a fertilizer or simply spread onto agricultural land, but the introduction of tighter environmental controls on odour and water pollution means that some form of waste management is now required, which provides further incentives for waste-to-energy conversion.

The most attractive method of converting these waste materials to useful form is anaerobic digestion which gives biogas that can be used as a fuel for internal combustion engines, to generate electricity from small gas turbines, burnt directly for cooking, or for space and water heating.

Forestry Residues

Forestry residues are generated by operations such as thinning of plantations, clearing for logging roads, extracting stem-wood for pulp and timber, and natural attrition. Harvesting may occur as thinning in young stands, or cutting in older stands for timber or pulp that also yields tops and branches usable for biomass energy. Harvesting operations usually remove only 25 to 50 percent of the volume, leaving the residues available as biomass for energy.

Stands damaged by insects, disease or fire are additional sources of biomass. Forest residues normally have low density and fuel values that keep transport costs high, and so it is economical to reduce the biomass density in the forest itself.

Wood Wastes

Wood processing industries primarily include sawmilling, plywood, wood panel, furniture, building component, flooring, particle board, moulding, jointing and craft industries. Wood wastes generally are concentrated at the processing factories, e.g. plywood mills and sawmills. The amount of waste generated from wood processing industries varies from one type industry to another depending on the form of raw material and finished product.

Generally, the waste from wood industries such as saw millings and plywood, veneer and others are sawdust, off-cuts, trims and shavings. Sawdust arise from cutting, sizing, re-sawing, edging, while trims and shaving are the consequence of trimming and smoothing of wood. In general, processing of 1,000 kg of wood in the furniture industries will lead to waste generation of almost half (45 %), i.e. 450 kg of wood. Similarly, when processing 1,000 kg of wood in sawmill, the waste will amount to more than half (52 %), i.e. 520 kg wood.

Industrial Wastes

The food industry produces a large number of residues and by-products that can be used as biomass energy sources. These waste materials are generated from all sectors of the food industry with everything from meat production to confectionery producing waste that can be utilised as an energy source.

Solid wastes include peelings and scraps from fruit and vegetables, food that does not meet quality control standards, pulp and fibre from sugar and starch extraction, filter sludges and coffee grounds. These wastes are usually disposed of in landfill dumps.

Liquid wastes are generated by washing meat, fruit and vegetables, blanching fruit and vegetables, pre-cooking meats, poultry and fish, cleaning and processing operations as well as wine making.

These waste waters contain sugars, starches and other dissolved and solid organic matter. The potential exists for these industrial wastes to be anaerobically digested to produce biogas, or fermented to produce ethanol, and several commercial examples of waste-to-energy conversion already exist.

Pulp and paper industry is considered to be one of the highly polluting industries and consumes large amount of energy and water in various unit operations. The wastewater discharged by this industry is highly heterogeneous as it contains compounds from wood or other raw materials, processed chemicals as well as compound formed during processing.  Black liquor can be judiciously utilized for production of biogas using anaerobic UASB technology.

Municipal Solid Wastes and Sewage

Millions of tonnes of household waste are collected each year with the vast majority disposed of in open fields. The biomass resource in MSW comprises the putrescibles, paper and plastic and averages 80% of the total MSW collected. Municipal solid waste can be converted into energy by direct combustion, or by natural anaerobic digestion in the engineered landfill. At the landfill sites the gas produced by the natural decomposition of MSW (approximately 50% methane and 50% carbon dioxide) is collected from the stored material and scrubbed and cleaned before feeding into internal combustion engines or gas turbines to generate heat and power. The organic fraction of MSW can be anaerobically stabilized in a high-rate digester to obtain biogas for electricity or steam generation.

Sewage is a source of biomass energy that is very similar to the other animal wastes. Energy can be extracted from sewage using anaerobic digestion to produce biogas. The sewage sludge that remains can be incinerated or undergo pyrolysis to produce more biogas.

A Primer on Biofuels

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The term ‘Biofuel’ refers to liquid or gaseous fuels for the transport sector that are predominantly produced from biomass. A variety of fuels can be produced from biomass resources including liquid fuels, such as ethanol, methanol, biodiesel, Fischer-Tropsch diesel, and gaseous fuels, such as hydrogen and methane. The biomass resource base for biofuel production is composed of a wide variety of forestry and agricultural resources, industrial processing residues, and municipal solid and urban wood residues.

The agricultural resources include grains used for biofuels production, animal manures and residues, and crop residues derived primarily from corn and small grains (e.g., wheat straw). A variety of regionally significant crops, such as cotton, sugarcane, rice, and fruit and nut orchards can also be a source of crop residues. The forest resources include residues produced during the harvesting of forest products, fuelwood extracted from forestlands, residues generated at primary forest product processing mills, and forest resources that could become available through initiatives to reduce fire hazards and improve forest health. Municipal and urban wood residues are widely available and include a variety of materials — yard and tree trimmings, land-clearing wood residues, wooden pallets, organic wastes, packaging materials, and construction and demolition debris.

Globally, biofuels are most commonly used to power vehicles, heat homes, and for cooking. Biofuel industries are expanding in Europe, Asia and the Americas. Biofuels are generally considered as offering many priorities, including sustainability, reduction of greenhouse gas emissions, regional development, social structure and agriculture, and security of supply.

First-generation biofuels are made from sugar, starch, vegetable oil, or animal fats using conventional technology. The basic feedstocks for the production of first-generation biofuels come from agriculture and food processing. The most common first-generation biofuels are:

• Biodiesel: extraction with or without esterification of vegetable oils from seeds of plants like soybean, oil palm, oilseed rape and sunflower or residues including animal fats derived from rendering applied as fuel in diesel engines
• Bioethanol: fermentation of simple sugars from sugar crops like sugarcane or from starch crops like maize and wheat applied as fuel in petrol engines
• Bio-oil: thermo-chemical conversion of biomass. A process still in the development phase
• Biogas: anaerobic fermentation or organic waste, animal manures, crop residues an energy crops applied as fuel in engines suitable for compressed natural gas.

First-generation biofuels can be used in low-percentage blends with conventional fuels in most vehicles and can be distributed through existing infrastructure. Some diesel vehicles can run on 100 % biodiesel, and ‘flex-fuel’ vehicles are already available in many countries around the world.

Second-generation biofuels are derived from non-food feedstock including lignocellulosic biomass like crop residues or wood. Two transformative technologies are under development.

• Biochemical: modification of the bio-ethanol fermentation process including a pre-treatment procedure
• Thermochemical: modification of the bio-oil process to produce syngas and methanol, Fisher-Tropsch diesel or dimethyl ether (DME).

Advanced conversion technologies are needed for a second generation of biofuels. The second generation technologies use a wider range of biomass resources – agriculture, forestry and waste materials. One of the most promising second-generation biofuel technologies – ligno-cellulosic processing (e. g. from forest materials) – is already well advanced. Pilot plants have been established in the EU, in Denmark, Spain and Sweden.

Third-generation biofuels may include production of bio-based hydrogen for use in fuel cell vehicles, e.g. Algae fuel, also called oilgae. Algae are low-input, high-yield feedstocks to produce biofuels.

Major Issues in Biomass Energy Projects

The issues enumerated below are not geography-specific and are usually a matter of concern for most of the biomass energy projects:

1. Large Project Costs: In India, a 1 MW gasification plant usually costs about USD 1-1.5 million. A combustion-based 1 MW plant would need a little more expenditure, to the tune of USD 1-2 million. An anaerobic digestion-based plant of the same capacity, on the other hand, could range anywhere upwards USD 3 million. Such high capital costs prove to be a big hurdle for any entrepreneur or clean-tech enthusiast to come forward and invest into these technologies.
2. Low Conversion Efficiencies: In general, efficiencies of combustion-based systems are in the range of 20-25% and gasification-based systems are considered even poorer, with their efficiencies being in the range of a measly10-15%. The biomass resources themselves are low in energy density, and such poor system efficiencies could add a double blow to the entire project.
3. Dearth of Mature Technologies: Poor efficiencies call for a larger quantum of resources needed to generate a unit amount of energy. Owing to this reason, investors and project developers find it hard to go for such plants on a larger scale. Moreover, the availability of only a few reliable technology and operation & maintenance service providers makes these technologies further undesirable. Gasification technology is still limited to scales lesser than 1 MW in most parts of the world. Combustion-based systems have although gone upwards of 1 MW, a lot many are now facing hurdles because of factors like unreliable resource chain, grid availability, and many others.
4. Lack of Funding Options: Financing agencies usually give a tough time to biomass project developers as compared to what it takes to invest in other renewable energy technologies.
5. Non-Transparent Trade Markets: Usually, the biomass energy resources are obtained through forests, farms, industries, animal farms etc. There is no standard pricing mechanism for such resources and these usually vary from vendor to vendor, even with the same resource in consideration.
6. High Risks / Low Pay-Backs: Biomass energy projects are not much sought-after owing to high project risks which could entail from failed crops, natural disasters, local disturbances, etc.
7. Resource Price Escalation: Unrealistic fuel price escalation too is a major cause of worry for the plant owners. Usually, an escalation of 3-5% is considered while carrying out the project’s financial modelling. However, it has been observed that in some cases, the rise has been as staggering as 15-20% per annum, forcing the plants to shut down.

Contributed by Setu Goyal, TERI University (New Delhi) who can be reached at setu.goyal@gmail.com)

 

 

Biomass Combined Heat and Power (CHP) Systems

Combined Heat and Power (CHP) is the simultaneous generation of multiple forms of useful energy (usually mechanical and thermal) in a single, integrated system. In conventional electricity generation systems, about 35% of the energy potential contained in the fuel is converted on average into electricity, whilst the rest is lost as waste heat. CHP systems use both electricity and heat and therefore can achieve an efficiency of up to 90%.

CHP systems consist of a number of individual components—prime mover (heat engine), generator, heat recovery, and electrical interconnection—configured into an integrated whole. Prime movers for CHP units include reciprocating engines, combustion or gas turbines, steam turbines, microturbines, and fuel cells.

A typical CHP system provides:

• Distributed generation of electrical and/or mechanical power.
• Waste-heat recovery for heating, cooling, or process applications.
• Seamless system integration for a variety of technologies, thermal applications, and fuel types.

The success of any biomass-fuelled CHP project is heavily dependent on the availability of a suitable biomass feedstock freely available in urban and rural areas.

Rural Resources	Urban Resources
Forest residues	Urban wood waste
Wood wastes	Municipal solid wastes
Crop residues	Agro-industrial wastes
Energy crops	Food processing residues
Animal manure	Sewage

Technology Options

Reciprocating or internal combustion engines (ICEs) are among the most widely used prime movers to power small electricity generators. Advantages include large variations in the size range available, fast start-up, good efficiencies under partial load efficiency, reliability, and long life.

Steam turbines are the most commonly employed prime movers for large power outputs. Steam at lower pressure is extracted from the steam turbine and used directly or is converted to other forms of thermal energy. System efficiencies can vary between 15 and 35% depending on the steam parameters.

Co-firing of biomass with coal and other fossil fuels can provide a short-term, low-risk, low-cost option for producing renewable energy while simultaneously reducing the use of fossil fuels. Biomass can typically provide between 3 and 15 percent of the input energy into the power plant. Most forms of biomass are suitable for co-firing.

Steam engines are also proven technology but suited mainly for constant speed operation in industrial environments. Steam engines are available in different sizes ranging from a few kW to more than 1 MW_e.

A gas turbine system requires landfill gas, biogas, or a biomass gasifier to produce the gas for the turbine. This biogas must be carefully filtered of particulate matter to avoid damaging the blades of the gas turbine.  

Stirling engines utilize any source of heat provided that it is of sufficiently high temperature. A wide variety of heat sources can be used but the Stirling engine is particularly well-suited to biomass fuels. Stirling engines are available in the 0.5 to 150 kW_e range and a number of companies are working on its further development.

A micro-turbine recovers part of the exhaust heat for preheating the combustion air and hence increases overall efficiency to around 20-30%. Several competing manufacturers are developing units in the 25-250kWe range. Advantages of micro-turbines include compact and light weight design, a fairly wide size range due to modularity, and low noise levels.

Fuel cells are electrochemical devices in which hydrogen-rich fuel produces heat and power. Hydrogen can be produced from a wide range of renewable and non-renewable sources. A future high temperature fuel cell burning biomass might be able to achieve greater than 50% efficiency.

Conclusions

CHP technologies are well suited for Clean Development Mechanism (CDM) and sustainable development projects, because they are, in general, socio-economically attractive and technologically mature and reliable. In developing countries, cogeneration can easily be integrated in many industries, especially agriculture and food-processing, taking advantage of the biomass residues of the production process. This has the dual benefits of lowering fuel costs and solving waste disposal issues.

 

Woody Biomass Utilization and Sustainability

Harvesting practices remove only a small portion of branches and tops leaving sufficient biomass to conserve organic matter and nutrients. Moreover, the ash obtained after combustion of biomass compensates for nutrient losses by fertilizing the soil periodically in natural forests as well as fields. The impact of forest biomass utilization on the ecology and biodiversity has been found to be insignificant. Infact, forest residues are environmentally beneficial because of their potential to replace fossil fuels as an energy source.

Plantation of energy crops on abandoned agricultural land will lead to an increase in species diversity. The creation of structurally and species diverse forests helps in reducing the impacts of insects, diseases and weeds. Similarly the artificial creation of diversity is essential when genetically modified or genetically identical species are being planted. Short-rotation crops give higher yields than forests so smaller tracts are needed to produce biomass which results in the reduction of area under intensive forest management. An intelligent approach in forest management will go a long way in the realization of sustainability goals.

Improvements in agricultural practices promises to increased biomass yields, reductions in cultivation costs, and improved environmental quality. Extensive research in the fields of plant genetics, analytical techniques, remote sensing and geographic information systems (GIS) will immensely help in increasing the energy potential of biomass feedstock.

Bioenergy systems offer significant possibilities for reducing greenhouse gas emissions due to their immense potential to replace fossil fuels in energy production. Biomass reduces emissions and enhances carbon sequestration since short-rotation crops or forests established on abandoned agricultural land accumulate carbon in the soil. Bioenergy usually provides an irreversible mitigation effect by reducing carbon dioxide at source, but it may emit more carbon per unit of energy than fossil fuels unless biomass fuels are produced unsustainably.

Biomass can play a major role in reducing the reliance on fossil fuels by making use of thermo-chemical conversion technologies. In addition, the increased utilization of biomass-based fuels will be instrumental in safeguarding the environment, generation of new job opportunities, sustainable development and health improvements in rural areas. The development of efficient biomass handling technology, improvement of agro-forestry systems and establishment of small and large-scale biomass-based power plants can play a major role in rural development. Biomass energy could also aid in modernizing the agricultural economy.

A large amount of energy is expended in the cultivation and processing of crops like sugarcane, coconut, and rice which can met by utilizing energy-rich residues for electricity production. The integration of biomass-fueled gasifiers in coal-fired power stations would be advantageous in terms of improved flexibility in response to fluctuations in biomass availability and lower investment costs. The growth of the bioenergy industry can also be achieved by laying more stress on green power marketing.

Carbon Sequestration and Biochar

Biochar sequestration is considered carbon negative as it results in a net decrease in atmospheric carbon dioxide over centuries or millennia time scales. Instead of allowing the organic matter to decompose and emit CO₂, pyrolysis can be used to sequester the carbon and  remove circulating carbon dioxide from the atmosphere and stores it in virtually permanent soil carbon pools, making it a carbon-negative process.

According to Johannes Lehmann of Cornell University, biochar sequestration could make a big difference in the fossil fuel emissions worldwide and act as a major player in the global carbon market with its robust, clean and simple production technology. The use of pyrolysis also provides an opportunity for the processing of agricultural residues, wood wastes and municipal solid waste into useful clean energy. Although some  organic matter is necessary for agricultural soil to maintain its productivity, much of the agricultural waste can be turned directly into biochar, bio-oil, and syngas. Pyrolysis transforms organic material such as agricultural residues and wood chips into three main components: syngas, bio-oil and biochar (which contain about 60 per cent of the carbon contained in the biomass.

Primary Biomass Conversion Technologies – Thermochemical

A wide range of technologies exists to convert the energy stored in biomass to more useful forms of energy. These technologies can be classified according to the principal energy carrier produced in the conversion process. Carriers are in the form of heat, gas, liquid and/or solid products, depending on the extent to which oxygen is admitted to the conversion process (usually as air). The three principal methods of thermo-chemical conversion corresponding to each of these energy carriers are combustion in excess air, gasification in reduced air, and pyrolysis in the absence of air.

Conventional combustion technologies raise steam through the combustion of biomass. This steam may then be expanded through a conventional turbo-alternator to produce electricity. A number of combustion technology variants have been developed. Underfeed stokers are suitable for small scale boilers up to 6 MWth. Grate type boilers are widely deployed. They have relatively low investment costs, low operating costs and good operation at partial loads. However, they can have higher NOx emissions and decreased efficiencies due to the requirement of excess air, and they have lower efficiencies.

Fluidized bed combustors (FBC), which use a bed of hot inert material such as sand, are a more recent development. Bubbling FBCs are generally used at 10-30 MWth capacity, while Circulating FBCs are more applicable at larger scales. Advantages of FBCs are that they can tolerate a wider range of poor quality fuel, while emitting lower NOx levels.

Gasification of biomass takes place in a restricted supply of oxygen and occurs through initial devolatilization of the biomass, combustion of the volatile material and char, and further reduction to produce a fuel gas rich in carbon monoxide and hydrogen. This combustible gas has a lower calorific value than natural gas but can still be used as fuel for boilers, for engines, and potentially for combustion turbines after cleaning the gas stream of tars and particulates. If gasifiers are ‘air blown’, atmospheric nitrogen dilutes the fuel gas to a level of 10-14 percent that of the calorific value of natural gas. Oxygen and steam blown gasifiers produce a gas with a somewhat higher calorific value. Pressurized gasifiers are under development to reduce the physical size of major equipment items.

A variety of gasification reactors have been developed over several decades. These include the smaller scale fixed bed updraft, downdraft and cross flow gasifiers, as well as fluidized bed gasifiers for larger applications. At the small scale, downdraft gasifiers are noted for their relatively low tar production, but are not suitable for fuels with low ash melting point (such as straw). They also require fuel moisture levels to be controlled within narrow levels.

Pyrolysis is the term given to the thermal degradation of wood in the absence of oxygen. It enables biomass to be converted to a combination of solid char, gas and a liquid bio-oil. Pyrolysis technologies are generally categorized as “fast” or “slow” according to the time taken for processing the feed into pyrolysis products. These products are generated in roughly equal proportions with slow pyrolysis. Using fast pyrolysis, bio-oil yield can be as high as 80 percent of the product on a dry fuel basis. Bio-oil can act as a liquid fuel or as a feedstock for chemical production. A range of bio-oil production processes are under development, including fluid bed reactors, ablative pyrolysis, entrained flow reactors, rotating cone reactors, and vacuum pyrolysis.

Biomass Energy and its Importance

Biomass can play a dual role in greenhouse gas mitigation related to the objectives of the UNFCCC, i.e. as an energy source to substitute for fossil fuels and as a carbon store. However, compared to the maintenance and enhancement of carbon sinks and reservoirs, it appears that the use of bioenergy has so far received less attention as a means of mitigating climate change. Modern bioenergy options offer significant, cost-effective and perpetual opportunities toward meeting emission reduction targets while providing additional ancillary benefits. Moreover, via the sustainable use of the accumulated carbon, bioenergy has the potential for resolving some of the critical issues surrounding long-term maintenance of biotic carbon stocks.

It has become clear that biomass can contribute substantially to GHG mitigation through both reductions of fossil carbon emissions and long-term storage of carbon in biomass. All forms of biomass utilization can be considered part of a closed carbon cycle. The mass of biospheric carbon involved in the global carbon cycle provides a scale for the potential of biomass mitigation options; whereas fossil fuel combustion accounts for some 6 Gigatons of carbon (GtC) release to the atmosphere annually, the net amount of carbon taken up from and released to the atmosphere by terrestrial plants is around 60 GtC annually (corresponding to a gross energy content of approximately 2100 EJ p.a., of which bioenergy is a part), and an estimated 600 GtC is stored in the terrestrial living biomass.

Biomass Pyrolysis

Pyrolysis is the thermal decomposition of biomass occurring in the absence of oxygen. It is the fundamental chemical reaction that is the precursor of both the combustion and gasification processes and occurs naturally in the first two seconds. The products of biomass pyrolysis include biochar, bio-oil and gases including methane, hydrogen, carbon monoxide, and carbon dioxide.  Depending on the thermal environment and the final temperature, pyrolysis will yield mainly biochar at low temperatures, less than 450 ⁰C, when the heating rate is quite slow, and mainly gases at high temperatures, greater than 800 ⁰C, with rapid heating rates. At an intermediate temperature and under relatively high heating rates, the main product is bio-oil.

Pyrolysis can be performed at relatively small scale and at remote locations which enhance energy density of the biomass resource and reduce transport and handling costs.  Heat transfer is a critical area in pyrolysis as the pyrolysis process is endothermic and sufficient heat transfer surface has to be provided to meet process heat needs. Pyrolysis offers a flexible and attractive way of converting solid biomass into an easily stored and transported liquid, which can be successfully used for the production of heat, power and chemicals.

A wide range of biomass feedstocks can be used in pyrolysis processes. The pyrolysis process is very dependent on the moisture content of the feedstock, which should be around 10%. At higher moisture contents, high levels of water are produced and at lower levels there is a risk that the process only produces dust instead of oil. High-moisture waste streams, such as sludge and meat processing wastes, require drying before subjecting to pyrolysis.

Biomass pyrolysis has been attracting much attention due to its high efficiency and good environmental performance characteristics. It also provides an opportunity for the processing of agricultural residues, wood wastes and municipal solid waste into clean energy. In addition, biochar sequestration could make a big difference in the fossil fuel emissions worldwide and act as a major player in the global carbon market with its robust, clean and simple production technology.