Hemp as Biomass Energy Resourc

The Inspired Observer

Energy. We all use energy, and NEED it. There are many forms of energy. Some are clean and healthy for the environment, some are not.

There are 2 sources of energy – non-renewable and renewable.

Non-renewable sources of energy include fossil fuels and uranium (which is not a fossil fuel). Combustive fossil fuels emit dangerous elements into the air and environment – sulfur dioxide and carbon monoxide. These are products that are the cause of pollution and acid rain.

Renewable sources of energy include hydropower, geothermal, solar, and biomass. These create less pollution and are cleaner to process.

Let’s look at biomass. Biomass, renewable energy, is biological material from living or recently living organisms. It can be used directly or converted to create other forms of energy. Examples of biomass are wood, crops, food waste, vegetable oils, and hemp.

In the 1900s Henry Ford, and others, realized the importance of…

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Biomass Energy Sector in India

Panchabuta-Renewable Energy & Cleantech in India

According to reports, Biomass power producers are in a quandary with input costs, operations and maintenance costs growing and tariff structure remaining stagnant, thereby making many projects across the country financially unviable.

The representative body of biomass producers, the Indian Biomass Power Association has written a letter to the Union Minister for New and Renewable Energy, Dr Farooq Abdullah, seeking his attention and intervention in addressing their concerns.

Nearly half of the installed capacity of 1,100 MW across several States is lying idle and there is demand-supply mismatch, according to Mr D. Radhakrishna, Secretary-General of IBPA.

Representatives of the association and biomass producers told Business Line that the situation needs to be addressed immediately as the recent requests made to the Central Electricity Regulatory Commission (CERC) have not been successful.

The producers use a wide range of agriculture waste such as rice and coconut husk and forest waste as…

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Rice Husk Power Heralding Change in India

Stephanie Hanson

Originally published in ecomagination:

In Bihar, one of the poorest states in India, 85 percent of people are not connected to the electricity grid. Households use kerosene lamps when they can afford it, and businesses use expensive and dirty diesel generators.

Some view this “energy poverty” as a development problem. Others view it as an environmental problem. The founders of Bihar-based Husk Power Systems view it as an opportunity to build a social enterprise.

The company realized that one waste product in Bihar—rice husks—could be used to power a small biomass gasifier. Along with rice husks, they also use mustard stems, corncobs, grasses, and other agricultural residue. After five months of R&D, they developed a system that could produce 32 kilowatts of power by burning 50 kilograms of rice husk per hour. In the last four years, they’ve installed over 80 biomass mini-plants across Bihar, bringing power to more…

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Thailand’s Biomass Energy Scenario

Thailand’s annual energy consumption has risen sharply during the past decade and will continue its upward trend in the years to come. While energy demand has risen sharply, domestic sources of supply are limited, thus forcing a significant reliance on imports. To face this increasing demand, Thailand needs to produce more energy from its own renewable resources, particularly biomass wastes derived from agro-industry, such as bagasse, rice husk, wood chips, livestock and municipal wastes.

In 2005, total installed power capacity in Thailand was 26,430 MW. Renewable energy accounted for about 2 percent of the total installed capacity. In 2007, Thailand had about 777 MW of electricity from renewable energy that was sold to the grid. Several studies have projected that biomass wastes can cover up to 15 % of the energy demand in Thailand (Thailand-Danish Country Programme for Environmental Assistance 1998-2001, Ministry of Environment and Energy, 2000). These estimations are primarily made from biomass waste from the extraction part of agricultural activities, and for large scale agricultural processing of crops etc. – as for instance saw and palm oil mills – and do not include biomass wastes from SMEs in Thailand. Thus, the energy potential of biomass waste can be much larger if these resources are included. The major biomass resources in Thailand include the following:

• Woody biomass residues from forest plantations
• Agricultural residues (rice husk, bagasse, corn cobs, etc.)
• Wood residues from wood and furniture industries    (bark, sawdust, etc.)
• Biomass for ethanol production (cassava, sugar cane, etc.)
• Biomass for biodiesel production (palm oil, jatropha oil, etc.)
• Industrial wastewater from agro-industry
• Livestock manure
• Municipal solid wastes and sewage

Thailand’s vast biomass potential has been partially exploited through the use of traditional as well as more advanced conversion technologies for biogas, power generation, and biofuels. Rice, sugar, palm oil, and wood-related industries are the major potential biomass energy sources. The country has a fairly large biomass resource base of about 60 million tons generated each year that could be utilized for energy purposes, such as rice, sugarcane, rubber sheets, palm oil and cassava. Biomass has been a primary source of energy for many years, used for domestic heating and industrial cogeneration. For example, paddy husks are burned to produce steam for turbine operation in rice mills; bagasse and palm residues are used to produce steam and electricity for on-site manufacturing process; and rubber wood chips are burned to produce hot air for rubber wood seasoning.

In addition to biomass residues, wastewater containing organic matters from livestock farms and industries has increasingly been used as a potential source of biomass energy. Thailand’s primary biogas sources are pig farms and residues from food processing. The production potential of biogas from industrial wastewater from palm oil industries, tapioca starch industries, food processing industries, and slaughter industries is also significant. The energy-recovery and environmental benefits that the KWTE waste to energy project has already delivered is attracting keen interest from a wide range of food processing industries around the world.

Vermicomposting

Vermicomposting is a type of composting in which certain species of earthworms are used to enhance the process of organic waste conversion and produce a better end-product. Vermicomposting is a mesophilic process utilizing microorganisms and earthworms. Earthworms feeds the organic waste materials and passes it through their digestive system and gives out in a granular form (cocoons) which is known as vermicompost. Like regular compost, vermicompost also benefits the environment by reducing the need for chemical fertilizers and decreasing the amount of waste going to landfills/dumpsites.

Vermicompost is primarily earthworm excrement, called castings, which can improve biological, chemical, and physical properties of the soil. The chemical secretions in the earthworm’s digestive tract help break down soil and organic matter, so the castings contain more nutrients that are immediately available to plants.

Earthworms consume various organic wastes and reduce the volume by 40–60 percent. Each earthworm weighs about 0.5 to 0.6 gram, eats waste equivalent to its body weight and produces cast equivalent to about 50 percent of the waste it consumes in a day. The moisture content of castings ranges between 32 and 66 percent and the pH is around 7.0. The worm castings contain higher percentage (almost twice) of both macro and micronutrients than the garden compost. About 2-3 kg of earthworms is required for 1000 kg of biomass, whereas about 1100 number earthworms are required for 1 m² area.

There are nearly 3600 types of earthworms and they are mainly divided into two types: (1) burrowing; and (2) non-burrowing. Red earthworm species like Eisenia foetida and

 are most efficient in compost making. The non-burrowing earthworms eat 10 percent soil and 90 percent organic waste materials; these convert the organic waste into vermicompost faster than the burrowing earthworms. They can tolerate temperatures ranging from 0 to 40°C but the regeneration capacity is more at 25 to 30°C and 40–45% moisture level in the pile. The burrowing types of earthworms come onto the soil surface only at night. These make holes in the soil up to a depth of 3.5 m and produce 5.6 kg casts by ingesting 90 percent soil and 10 percent organic waste.

A wide range of agricultural residues, all dry wastes, for example, straw, husk, dry leaves of crops and trees, stalks, vegetable wastes, weeds etc can be converted into vermicompost. In addition, animal manures, dairy and poultry wastes, food industry wastes, municipal solid wastes, biogas sludge and bagasse from sugarcane factories also serve as good raw materials for vermicomposting.

Ethanol Production via Biochemical Route

Ethanol from lignocellulosic biomass is produced mainly via biochemical routes. The three major steps involved are pretreatment, enzymatic hydrolysis, and fermentation as shown in Figure. Biomass is pretreated to improve the accessibility of enzymes. After pretreatment, biomass undergoes enzymatic hydrolysis for conversion of polysaccharides into monomer sugars, such as glucose and xylose. Subsequently, sugars are fermented to ethanol by the use of different microorganisms.

Pretreated biomass can directly be converted to ethanol by using the process called simultaneous saccharification and cofermentation (SSCF). Pretreatment is a critical step which enhances the enzymatic hydrolysis of biomass. Basically, it alters the physical and chemical properties of biomass and improves the enzyme access and effectiveness which may also lead to a change in crystallinity and degree of polymerization of cellulose. The internal surface area and pore volume of pretreated biomass are increased which facilitates substantial improvement in accessibility of enzymes. The process also helps in enhancing the rate and yield of monomeric sugars during enzymatic hydrolysis steps.

Pretreatment methods can be broadly classified into four groups – physical, chemical, physio-chemical and biological. Physical pretreatment processes employ the mechanical comminution or irradiation processes to change only the physical characteristics of biomass. The physio-chemical process utilizes steam or steam and gases, like SO2 and CO2. The chemical processes employs acids (H2SO4, HCl, organic acids etc) or alkalis (NaOH, Na2CO3, Ca(OH)2, NH3 etc). The acid treatment typically shows the selectivity towards hydrolyzing the hemicelluloses components, whereas alkalis have better selectivity for the lignin. The fractionation of biomass components after such processes help in improving the enzymes accessibility which is also important to the efficient utilization of enzymes.

The pretreated biomass is subjected to enzymatic hydrolysis using cellulase enzymes to convert the cellulose to fermentable sugars. Cellulase refers to a class of enzymes produced chiefly by fungi and bacteria which catalyzes the hydrolysis of cellulose by attacking the glycosidic linkages. Cellulase is mixture of mainly three different functional protein groups: exo-glucanase (Exo-G), endo-glucanase(Endo-G) and β-glucosidase (β-G). The functional proteins work synergistically in hydrolyzing the cellulose into the glucose. These sugars are further fermented using microorganism and are converted to ethanol. The microorganisms are selected based on their efficiency for ethanol productivity and higher product and inhibitors tolerance. Yeast Saccharomyces cerevisiae is used commercially to produce the ethanol from starch and sucrose.

Escherichia coli strain has also been developed recently for ethanol production by the first successful application of metabolic engineering. E. coli can consume variety of sugars and does not require the complex growth media but has very narrow operable range of pH. E. coli has higher optimal temperature than other known strains of bacteria.

The major cost components in bioethanol production from lignocellulosic biomass are the pretreatment and the enzymatic hydrolysis steps. In fact, these two process are someway interrelated too where an efficient pretreatment strategy can save substantial enzyme consumption. Pretreatment step can also affect the cost of other operations such as size reduction prior to pretreatment. Therefore, optimization of these two important steps, which collectively contributes about 70% of the total processing cost, are the major challenges in the commercialization of bioethanol from 2nd generation feedstock.

Enzyme cost is the prime concern in full scale commercialization. The trend in enzyme cost is encouraging because of enormous research focus in this area and the cost is expected to go downward in future, which will make bioethanol an attractive option considering the benefits derived its lower greenhouse gas emissions and the empowerment of rural economy.

Introduction to POME

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Palm Oil processing gives rise to highly polluting waste-water, known as Palm Oil Mill Effluent (POME), which is often discarded in disposal ponds, resulting in the leaching of contaminants that pollute the groundwater and soil, and in the release of methane gas into the atmosphere. POME is an oily wastewater generated by palm oil processing mills and consists of various suspended components. This liquid waste combined with the wastes from steriliser condensate and cooling water is called palm oil mill effluent (POME). On average, for each ton of FFB (fresh fruit bunches) processed, a standard palm oil mill generate about 1 tonne of liquid waste with biochemical oxygen demand (BOD) 27 kg, chemical oxygen demand (COD) 62 kg, suspended solids (SS) 35 kg and oil and grease 6 kg

POME has a very high Biochemical Oxygen Demand (BOD) and Chemical Oxygen Demand (COD), which is 100 times more than the municipal sewage. POME is a non-toxic waste, as no chemical is added during the oil extraction process, but will pose environmental issues due to large oxygen depleting capability in aquatic system due to organic and nutrient contents. The high organic matter is due to the presence of different sugars such as arabinose, xylose, glucose, galactose and manose. The suspended solids in the POME are mainly oil-bearing cellulosic materials from the fruits. Since the POME is non-toxic as no chemical is added in the oil extraction process, it is a good source of nutrients for microorganisms.

Currently, recovery of renewable organic-based product is a new approach in managing POME. The technology is aimed to recover by-products such as volatile fatty acid, biogas and poly-hydroxyalkanoates to promote sustainability of the palm oil industry. In addition, it is envisaged that POME can be sustainably reused as a fermentation substrate in production of various metabolites through biotechnological advances. In addition, POME consists of high organic acids and is suitable to be used as a carbon source

Anaerobic digestion is widely adopted in the industry as a primary treatment for POME. Biogas is produced in the process in the amount of 20 m³per ton FFB. This effluent could be used for biogas production through anaerobic digestion. At many Palm-oil mills this process is already in place to meet water quality standards for industrial effluent. The gas, however, is flared off. Liquid effluents from Palm Oil mills in Southeast Asia can be used to generate power through gas turbines or gas-fired engines.

Different Strategies in Composting

The methodology of composting can be categorized into three major segments—anaerobic composting, aerobic composting, and vermicomposting. In anaerobic composting, the organic matter is decomposed in the absence of air. Organic matter may be collected in pits and covered with a thick layer of soil and left undisturbed six to eight months. The compost so formed may not be completely converted and may include aggregated masses.

Aerobic compostingis the process by which organic wastes are converted into compost or manure in presence of air and can be of different types. The most common is the Heap Method, where organic matter needs to be divided into three different types and to be placed in a heap one over the other, covered by a thin layer of soil or dry leaves. This heap needs to be mixed every week, and it takes about three weeks for conversion to take place. The process is same in the Pit Method, but carried out specially constructed pits. Mixing has to be done every 15 days, and there is no fixed time in which the compost may be ready. Berkley Method uses a labor-intensive technique and has precise requirements of the material to be composted. Easily biodegradable materials, such as grass, vegetable matter, etc., are mixed with animal matter in the ratio of 2:1. Compost is usually ready in 15 days.

Vermicomposting involves use of earthworms as natural and versatile bioreactors for the process of conversion. It is carried out in specially designed pits where earthworm culture also needs to be done. Vermicomposting is a precision-based option and requires overseeing of work by an expert. It is also a more expensive option (O&M costs especially are high). However, unlike the above two options, it is a completely odorless process making it a preferred solution in residential areas. It also has an extremely high rate of conversion, so quality of the end product is very high with rich macro and micronutrients. The end product also has the advantage that it can be dried and stored safely for a longer period of time.

Biomass Energy Resources in Indonesia

With Indonesia’s recovery from the Asian financial crisis of 1998, energy consumption has grown rapidly in past decade. The priority of the Indonesian energy policy is to reduce oil consumption and to use renewable energy. For power generation, it is important to increase electricity power in order to meet national demand and to change fossil fuel consumption by utilization of biomass wastes. The development of renewable energy is one of priority targets in Indonesia.

It is estimated that Indonesia produces 146.7 million tons of biomass per year, equivalent to about 470 GJ/y. The source of biomass energy is scattered all over the country, but the big potential in concentrated scale can be found in the Island of Kalimantan, Sumatera, Irian Jaya and Sulawesi. Studies estimate the electricity generation potential from the roughly 150 Mt of biomass residues produced per year to be about 50 GW or equivalent to roughly 470 GJ/year. These studies assume that the main source of biomass energy in Indonesia will be rice residues with a technical energy potential of 150 GJ/year. Other potential biomass sources are rubber wood residues (120 GJ/year), sugar mill residues (78 GJ/year), palm oil residues (67 GJ/year), and less than 20 GJ/year in total from plywood and veneer residues, logging residues, sawn timber residues, coconut residues, and other agricultural wastes.

Sustainable and renewable natural resources such as biomass can supply potential raw materials for energy conversion. In Indonesia, they comprise variable-sized wood from forests (i.e. natural forests, plantations and community forests that commonly produce small-diameter logs used as firewood by local people), woody residues from logging and wood industries, oil-palm shell waste from crude palm oil factories, coconut shell wastes from coconut plantations, as well as skimmed coconut oil and straw from rice cultivation.

The major crop residues to be considered for power generation in Indonesia are palm oil sugar processing and rice processing residues. Currently, 67 sugar mills are in operation in Indonesia and eight more are under construction or planned. The mills range in size of milling capacity from less than 1,000 tons of cane per day to 12,000 tons of cane per day. Current sugar processing in Indonesia produces 8 millions MT bagasse and 11.5 millions MT canes top and leaves. There are 39 palm oil plantations and mills currently operating in Indonesia, and at least eight new plantations are under construction. Most palm oil mills generate combined heat and power from fibres and shells, making the operations energy self –efficient. However, the use of palm oil residues can still be optimized in more energy efficient systems.

Other potential source of biomass energy can also come from municipal wastes. The quantity of city or municipal wastes in Indonesia is comparable with other big cities of the world. Most of these wastes are originated from household in the form of organic wastes from the kitchen. At present the wastes are either burned at each household or collected by the municipalities and later to be dumped into a designated dumping ground or landfill. Although the government is providing facilities to collect and clean all these wastes, however, due to the increasing number of populations coupled with inadequate number of waste treatment facilities in addition to inadequate amount of allocated budget for waste management, most of big cities in Indonesia had been suffering from the increasing problem of waste disposals.

The current pressure for cost savings and competitiveness in Indonesia’s most important biomass-based industries, along with the continually growing power demands of the country signal opportunities for increased exploitation of biomass wastes for power generation.

Biomass Resources from Sugar Industry

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Sugarcane is one of the most promising agricultural sources of biomass energy in the world. It is the most appropriate agricultural energy crop in most Cane producing countries due to its resistance to cyclonic winds, drought, pests and diseases, and its geographically widespread cultivation. Due to its high energy-to-volume ratio, it is considered one of nature’s most effective storage devices for solar energy and the most economically significant energy crop. The climatic and physiological factors that limit its cultivation to tropical and sub-tropical regions have resulted in its concentration in developing countries, and this, in turn, gives these countries a particular role in the world’s transition to sustainable use of natural resources.

 According to the International Sugar Organization (ISO), Sugarcane is a highly efficient converter of solar energy, and has the highest energy-to-volume ratio among energy crops. Indeed, it gives the highest annual yield of biomass of all species. Roughly, 1 ton of Sugarcane biomass-based on Bagasse, foliage and ethanol output – has an energy content equivalent to one barrel of crude oil.   Sugarcane produces mainly two types of biomass, Cane Trash and Bagasse. Cane Trash is the field residue remaining after harvesting the Cane stalk and Bagasse is the milling by-product which remains after extracting the Sugar from the stalk. The potential energy value of these residues has traditionally been ignored by policy-makers and masses in developing countries. However, with rising fossil fuel prices and dwindling firewood supplies, this material is increasingly viewed as a valuable Renewable Energy resource.

Sugar mills have been using Bagasse to generate steam and electricity for internal plant requirements while Cane Trash remains underutilized to a great extent. Cane Trash and Bagasse are produced during the harvesting and milling process of Sugar Cane which normally lasts 6 to 7 months.

Around the world, a portion of the Cane Trash is collected for sale to feed mills, while freshly cut green tops are sometimes collected for farm animals. In most cases, however, the residues are burned or left in the fields to decompose. Cane Trash, consisting of Sugarcane tops and leaves can potentially be converted into around 1kWh/kg, but is mostly burned in the field due to its bulkiness and its related high cost for collection/transportation.

 On the other hand, Bagasse has been traditionally used as a fuel in the Sugar mill itself, to produce steam for the process and electricity for its own use. In general, for every ton of Sugarcane processed in the mill, around 190 kg Bagasse is produced. Low pressure boilers and low efficiency steam turbines are commonly used in developing countries. It would be a good business proposition to upgrade the present cogeneration systems to highly efficient, high pressure systems with higher capacities to ensure utilization of surplus Bagasse.

Composting Guidelines

Image by Getty Images via @daylife

It seems everyone is concerned about the environment and trying to reduce their “carbon footprint”.  I hope this trend will continue and grow as a nationwide way to live and not turn into a fad.  Composting has been around for MANY years.  Composting is a great way to keep biodegradables out of the landfill and to reap the reward of some fabulous “black gold”.  That’s what master gardeners call compost and it’s great for improving your soil.  Plants love it.  Check out 10 Rules to Remember About Composting.

1. Layer your compost bin with dry and fresh ingredients: The best way to start a compost pile is to make yourself a bin either with wood or chicken wire.  Layering fresh grass clippings and dried leaves is a great start.
2. Remember to turn your compost pile: As the ingredients in your compost pile start to biodegrade they will start to get hot.  To avoid your compost pile rotting and stinking you need to turn the pile to aerate it.  This addition of air into the pile will speed up the decomposition.
3. Add water to your compost pile: Adding water will also speed up the process of scraps turning into compost.  Don’t add too much water, but if you haven’t gotten any rain in a while it’s a good idea to add some water to the pile just to encourage it along.
4. Don’t add meat scraps to your pile: Vegetable scraps are okay to add to your compost pile, but don’t add meat scraps.  Not only do they stink as they rot, but they will attract unwanted guests like raccoons that will get into your compost bin and make a mess of it.
5. If possible have more than one pile going: Since it takes time for raw materials to turn into compost you may want to have multiple piles going at the same time.  Once you fill up the first bin start a second one and so on.  That way you can allow the ingredient in the first pile to completely transform into compost and still have a place to keep putting your new scraps and clippings.  This also allows you to always keep a supply of compost coming for different planting seasons.
6. Never put trash in your compost pile: Just because something says that it is recyclable it doesn’t mean that it should necessarily go into the compost bin.  For example, newspapers will compost and can be put into a compost pile, but you will want to shred the newspapers and not just toss them in the bin in a stack.  Things like plastic and tin should not be put into a compost pile, but can be recycled in other ways.
7. Allow your compost to complete the composting process before using: It might be tempting to use your new compost in your beds as soon as it starts looking like black soil, but you need to make sure that it’s completely done composting otherwise you could be adding weed seeds into your beds and you will not be happy with the extra weeds that will pop up.
8. Straw can be added if dried leaves are not available: Dried materials as well as green materials need to be added to a compost bin.  In the Fall you will have a huge supply of dried leaves, but what do you do if you don’t have any dried leaves?  Add straw or hay to the compost bin, but again these will often contain weed seeds so be careful to make sure they are completely composted before using them.
9. Egg Shells and Coffee grounds are a great addition: Not only potato skins are considered kitchen scraps.  Eggshells and coffee grounds are great additions to compost piles because they add nutrients that will enhance the quality of the end product.
10. Never put pet droppings in your compost pile: I’m sure you’ve heard that manure is great for your garden, but cow manure is cured for quite a while before used in a garden.  Pet droppings are far to hot and acidic for a home compost pile and will just make it stink.

Contributed by Roxanne Porter whose original blogpost can be viewed at http://www.nannypro.com/blog/10-rules-to-remember-about-composting/. 

Production of Cellulosic Ethanol

The production of biofuels from lignocellulosic feedstocks can be achieved through two very different processing routes. They are:

• Biochemical – in which enzymes and other micro-organisms are used to convert cellulose and hemicellulose components of the feedstocks to sugars prior to their fermentation to produce ethanol;
• Thermo-chemical – where pyrolysis/gasification technologies produce a synthesis gas (CO + H₂) from which a wide range of long carbon chain biofuels, such as synthetic diesel or aviation fuel, can be reformed.

Lignocellulosic biomass consists mainly of lignin and the polysaccharides cellulose and hemicellulose. Compared with the production of ethanol from first-generation feedstocks, the use of lignocellulosic biomass is more complicated because the polysaccharides are more stable and the pentose sugars are not readily fermentable by Saccharomyces cerevisiae. In order to convert lignocellulosic biomass to biofuels the polysaccharides must first be hydrolysed, or broken down, into simple sugars using either acid or enzymes. Several biotechnology-based approaches are being used to overcome such problems, including the development of strains of Saccharomyces cerevisiae that can ferment pentose sugars, the use of alternative yeast species that naturally ferment pentose sugars, and the engineering of enzymes that are able to break down cellulose and hemicellulose into simple sugars.

Lignocellulosic processing pilot plants have been established in the EU, in Denmark, Spain and Sweden. The world’s largest demonstration facility of lignocellulose ethanol (from wheat, barley straw and corn stover), with a capacity of 2.5 Ml, was first established by Iogen Corporation in Ottawa, Canada. Many other processing facilities are now in operation or planning throughout the world.

Ethanol from lignocellulosic biomass is produced mainly via biochemical routes. The three major steps involved are pretreatment, enzymatic hydrolysis, and fermentation as shown in Figure. Biomass is pretreated to improve the accessibility of enzymes. After pretreatment, biomass undergoes enzymatic hydrolysis for conversion of polysaccharides into monomer sugars, such as glucose and xylose. Subsequently, sugars are fermented to ethanol by the use of different microorganisms.

Pretreated biomass can directly be converted to ethanol by using the process called simultaneous saccharification and cofermentation (SSCF).  Pretreatment is a critical step which enhances the enzymatic hydrolysis of biomass. Basically, it alters the physical and chemical properties of biomass and improves the enzyme access and effectiveness which may also lead to a change in crystallinity and degree of polymerization of cellulose. The internal surface area and pore volume of pretreated biomass are increased which facilitates substantial improvement in accessibility of enzymes. The process also helps in enhancing the rate and yield of monomeric sugars during enzymatic hydrolysis steps.

Pretreatment methods can be broadly classified into four groups – physical, chemical, physio-chemical and biological. Physical pretreatment processes employ the mechanical comminution or irradiation processes to change only the physical characteristics of biomass. The physio-chemical process utilizes steam or steam and gases, like SO₂ and CO₂. The chemical processes employs acids (H₂SO₄, HCl, organic acids etc) or alkalis (NaOH, Na₂CO₃, Ca(OH)₂, NH₃ etc). The acid treatment typically shows the selectivity towards hydrolyzing the hemicelluloses components, whereas alkalis have better selectivity for the lignin. The fractionation of biomass components after such processes help in improving the enzymes accessibility which is also important to the efficient utilization of enzymes.

Presently, a ton of dry biomass typically yields 60-70 gallons of bioethanol. The major cost components in bioethanol production from lignocellulosic biomass are the pretreatment and the enzymatic hydrolysis steps. In fact, these two process are someway interrelated too where an efficient pretreatment strategy can save substantial enzyme consumption. Pretreatment step can also affect the cost of other operations such as size reduction prior to pretreatment. Therefore, optimization of these two important steps, which collectively contributes about 70% of the total processing cost, are the major challenges in the commercialization of bioethanol from 2^nd generation feedstock.