By Elton Alisson Agência FAPESP – Biorefineries, as are called the industrial complexes that produce fuel, electricity and chemicals from biomass, are becoming enterprise capable of converting a wide variety of materials, including agricultural waste, into several products. This process with more energy efficient, economic and environmental benefits compared to conventional technological processes that give rise to only one or two products.
According to Jonas Contiero, a professor at Universidade Estadual Paulista (UNESP), Campus of Rio Claro, the first biorefineries plants were characterized by production of ethyl alcohol by grinding dry grains such as raw materials and have a line of fixed production , which consists of ethyl alcohol in co-products and carbon dioxide. Later, began to emerge in second generation Biorefineries that use technology for grinding “wet”, which enables the production of various final products, depending on demand, using mainly grains as raw materials. There are currently undergoing research…
The term ‘Biofuel’ refers to liquid or gaseous fuels for the transport sector that are predominantly produced from biomass. A variety of fuels can be produced from biomass resources including liquid fuels, such as ethanol, methanol, biodiesel, Fischer-Tropsch diesel, and gaseous fuels, such as hydrogen and methane. The biomass resource base for biofuel production is composed of a wide variety of forestry and agricultural resources, industrial processing residues, and municipal solid and urban wood residues.
The agricultural resources include grains used for biofuels production, animal manures and residues, and crop residues derived primarily from corn and small grains (e.g., wheat straw). A variety of regionally significant crops, such as cotton, sugarcane, rice, and fruit and nut orchards can also be a source of crop residues. The forest resources include residues produced during the harvesting of forest products, fuelwood extracted from forestlands, residues generated at primary forest product processing mills, and forest resources that could become available through initiatives to reduce fire hazards and improve forest health. Municipal and urban wood residues are widely available and include a variety of materials — yard and tree trimmings, land-clearing wood residues, wooden pallets, organic wastes, packaging materials, and construction and demolition debris.
Globally, biofuels are most commonly used to power vehicles, heat homes, and for cooking. Biofuel industries are expanding in Europe, Asia and the Americas. Biofuels are generally considered as offering many priorities, including sustainability, reduction of greenhouse gas emissions, regional development, social structure and agriculture, and security of supply.
First-generation biofuels are made from sugar, starch, vegetable oil, or animal fats using conventional technology. The basic feedstocks for the production of first-generation biofuels come from agriculture and food processing. The most common first-generation biofuels are:
Biodiesel: extraction with or without esterification of vegetable oils from seeds of plants like soybean, oil palm, oilseed rape and sunflower or residues including animal fats derived from rendering applied as fuel in diesel engines
Bioethanol: fermentation of simple sugars from sugar crops like sugarcane or from starch crops like maize and wheat applied as fuel in petrol engines
Bio-oil: thermo-chemical conversion of biomass. A process still in the development phase
Biogas: anaerobic fermentation or organic waste, animal manures, crop residues an energy crops applied as fuel in engines suitable for compressed natural gas.
First-generation biofuels can be used in low-percentage blends with conventional fuels in most vehicles and can be distributed through existing infrastructure. Some diesel vehicles can run on 100 % biodiesel, and ‘flex-fuel’ vehicles are already available in many countries around the world.
Second-generation biofuels are derived from non-food feedstock including lignocellulosic biomass like crop residues or wood. Two transformative technologies are under development.
Biochemical: modification of the bio-ethanol fermentation process including a pre-treatment procedure
Thermochemical: modification of the bio-oil process to produce syngas and methanol, Fisher-Tropsch diesel or dimethyl ether (DME).
Advanced conversion technologies are needed for a second generation of biofuels. The second generation technologies use a wider range of biomass resources – agriculture, forestry and waste materials. One of the most promising second-generation biofuel technologies – ligno-cellulosic processing (e. g. from forest materials) – is already well advanced. Pilot plants have been established in the EU, in Denmark, Spain and Sweden.
Third-generation biofuels may include production of bio-based hydrogen for use in fuel cell vehicles, e.g. Algae fuel, also called oilgae. Algae are low-input, high-yield feedstocks to produce biofuels.
First-generation biofuels (produced primarily from food crops such as grains, sugar beet and oil seeds) are limited in their ability to achieve targets for oil-product substitution, climate change mitigation, and economic growth. Their sustainable production is under scanner, as is the possibility of creating undue competition for land and water used for food and fibre production.
The cumulative impacts of these concerns have increased the interest in developing biofuels produced from non-food biomass. Feedstocks from ligno-cellulosic materials include cereal straw, bagasse, forest residues, and purpose-grown energy crops such as vegetative grasses and short rotation forests. These second-generation biofuels could avoid many of the concerns facing first-generation biofuels and potentially offer greater cost reduction potential in the longer term.
The largest potential feedstock for ethanol is lignocellulosic biomass, which includes materials such as agricultural residues (corn stover, crop straws and bagasse), herbaceous crops (alfalfa, switchgrass), short rotation woody crops, forestry residues, waste paper and other wastes (municipal and industrial). Bioethanol production from these feedstocks could be an attractive alternative for disposal of these residues. Importantly, lignocellulosic feedstocks do not interfere with food security. Moreover, bioethanol is very important for both rural and urban areas in terms of energy security reason, environmental concern, employment opportunities, agricultural development, foreign exchange saving, socioeconomic issues etc.
Economically, lignocellulosic biomass has an advantage over other agriculturally important biofuels feedstocks such as corn starch, soybeans, and sugar cane, because it can be produced quickly and at significantly lower cost than food crops. Lignocellulosic biomass is an important component of the major food crops; it is the non-edible portion of the plant, which is currently underutilized, but could be used for biofuel production. In short, lignocellulosic biomass holds the key to supplying society’s basic needs for sustainable production of liquid transportation fuels without impacting the nation’s food supply.
In India, the leading biofuel feedstock today is sugarcane molasses, which is processed to yield bioethanol that can be blended into gasoline (petrol). Sugarcane requires good land and large amounts of irrigation water, which are difficult for the poor to obtain. The bioethanol industry buys its molasses feedstock from the sugar factories. Sugar is the main objective of the sugarcane industry; molasses are simply a byproduct. As such, the unreliability of supply of molasses is a major constraint to biofuels development based on this feedstock.
Even though India is an agrarian economy, the energy potential of agricultural residues has not been realized till now by policy-makers and masses. Most of the biomass wastes are inefficiently used for domestic purposes in absence of reliable and cheaper source of energy. The main crops produced in India are wheat, maize, rice, sorghum, sugarcane and barley. India is among the market leaders in the production of these crops and has tremendous potential to convert lignocellulosic crop residues into ethanol.